Experimental Investigation of a Passive Direct Polymer Electrolyte Fuel Cell Using L-Ascorbic Acid as a Fuel
DOI:
https://doi.org/10.31181/rme537Keywords:
Passive Direct Ascorbic Acid, Fuel Cell, AA Concentration, Torque; Orientation, TemperatureAbstract
The present study involves an experimental investigation of the electrochemical performance of a passive direct ascorbic acid fuel cell (DAAFC), evaluating its potential as a sustainable energy source. A single-cell assembly of DAAFC integrated with a Nafion® 117 membrane measuring 5 cm x 5 cm was fabricated and evaluated. The influence of variation in significant parameters, including ascorbic acid feed concentration, cell positioning (horizontal/vertical), bolt clamping torque, and operating temperature, was investigated. The outcome of the experiment highlights the importance of controlling these parameters for enhanced electrochemical performance of the passive DAAFC system. Different cell AA concentrations were fed to the system from 0.25 M to 1.75 M, at which the maximum power density of 0.633 mW/cm2 was obtained at 1.5 M. Further, this concentration was used for the remainder of the experimentation. For each condition of the cell parameter, a specific experimental procedure is followed to identify the optimum value of the selected parameter. The passive DAAFC shows optimum electrochemical performance when applied with 8 Nm of bolt torque. The horizontal cell orientation and 60°C operating temperature were identified as the optimum parameters among the experimental attributes. The cell produces a maximum power density of 0.838 mW/cm2 at 60°C among all experimental sets. These results demonstrate that careful optimisation of operating conditions significantly enhances the electrochemical performance of DAFC. The results show that each of these parameters significantly affects the electrochemical performance of the passive DAAFC. Moreover, the study confirms the potential of using ascorbic acid as an effective fuel for electricity generation, and the outcome of this study is expected to serve as a useful reference for guiding future research and development efforts in DAAFC systems.
References
Badwal, S., Giddey, S., Kulkarni, A., Goel, J., & Basu, S. (2015). Direct ethanol fuel cells for transport and stationary applications–A comprehensive review. Applied Energy, 145, 80-103. https://doi.org/10.1016/j.apenergy.2015.02.002
Bates, A., Mukherjee, S., Hwang, S., Lee, S. C., Kwon, O., Choi, G. H., & Park, S. (2013). Simulation and experimental analysis of the clamping pressure distribution in a PEM fuel cell stack. International Journal of Hydrogen Energy, 38(15), 6481-6493. https://doi.org/10.1016/j.ijhydene.2013.03.049
Berretti, E., Osmieri, L., Baglio, V., Miller, H. A., Filippi, J., Vizza, F., Santamaria, M., Specchia, S., Santoro, C., & Lavacchi, A. (2023). Direct alcohol fuel cells: a comparative review of acidic and alkaline systems. Electrochemical Energy Reviews, 6(1), 30. https://doi.org/10.1007/s41918-023-00189-3
Boni, M., Rao, S. S., & Srinivasulu, G. N. (2022). Experimental analysis of a two-cell passive direct methanol fuel cell stack. Korean Journal of Chemical Engineering, 39(1), 116-120. https://doi.org/10.1007/s11814-021-0897-y
Chadge, R. B., Shrivastava, N., Giri, J. P., & Ahire, P. (2016). Effect of ethanol concentration and cell orientation on the performance of passive direct ethanol fuel cell. In 2016 11th International Conference on Industrial and Information Systems (ICIIS) (pp. 215-217). IEEE. https://doi.org/10.1109/iciinfs.2016.8262938
Choun, M., Lee, H. J., & Lee, J. (2016). Positively charged carbon electrocatalyst for enhanced power performance of L-ascorbic acid fuel cells. Journal of energy chemistry, 25(5), 793-797. https://doi.org/10.1016/j.jechem.2016.05.006
Deutsch, J. C. (2000). Dehydroascorbic acid. Journal of chromatography A, 881(1-2), 299-307. https://doi.org/10.1016/s0021-9673(00)00166-7
Fujiwara, N., Yamazaki, S.-i., Siroma, Z., Ioroi, T., & Yasuda, K. (2007). l-Ascorbic acid as an alternative fuel for direct oxidation fuel cells. Journal of Power Sources, 167(1), 32-38. https://doi.org/10.1016/j.jpowsour.2007.02.023
Fujiwara, N., Yamazaki, S.-i., & Yasuda, K. (2011). Research and development on direct polymer electrolyte fuel cells. Journal of the Japan Petroleum Institute, 54(4), 237-247. https://doi.org/10.1627/jpi.54.237
Ha, S., Dunbar, Z., & Masel, R. (2006). Characterization of a high performing passive direct formic acid fuel cell. Journal of Power Sources, 158(1), 129-136. https://doi.org/10.1016/j.jpowsour.2005.09.048
Hasan, M. M. (2023). Environment-Friendly Ascorbic Acid Fuel Cell. Electrochem, 4(1), 31-41. https://doi.org/10.3390/electrochem4010003
Keramati, A., Hendrix, K., Nguyen, D., Gonzales, F., Waters, K., Fry‐Petit, A., & Haan, J. L. (2021). A non‐precious metal ascorbate fuel cell. International Journal of Energy Research, 45(7), 10821-10831. https://doi.org/10.1002/er.6565
Maiyalagan, T., & Pasupathi, S. (2010). Components for PEM fuel cells: An overview. In Materials Science Forum (Vol. 657, pp. 143-189). Trans Tech Publ. https://doi.org/10.4028/www.scientific.net/msf.657.143
Mallick, R. K., Thombre, S. B., & Shrivastava, N. K. (2015). A critical review of the current collector for passive direct methanol fuel cells. Journal of Power Sources, 285, 510-529. https://doi.org/10.1016/j.jpowsour.2015.03.089
Molavian, M. R., Abdolmaleki, A., & Eskandari, K. (2016). Theoretical investigation of proton-transfer in different membranes for PEMFC applications in low humidity conditions. Computational Materials Science, 122, 126-138. https://doi.org/10.1016/j.commatsci.2016.05.003
Muneeb, O., Do, E., Tran, T., Boyd, D., Huynh, M., Ghosn, G., & Haan, J. L. (2017). A direct ascorbate fuel cell with an anion exchange membrane. Journal of Power Sources, 351, 74-78. https://doi.org/10.1016/j.jpowsour.2017.03.068
Ong, B., Kamarudin, S., & Basri, S. (2017). Direct liquid fuel cells: A review. International Journal of Hydrogen Energy, 42(15), 10142-10157. https://doi.org/10.1016/j.ijhydene.2017.01.117
Pappenberger, G., & Hohmann, H.-P. (2013). Industrial Production of l-Ascorbic Acid (Vitamin C) and d-Isoascorbic Acid. Advances in Biochemical Engineering/Biotechnology, 143, 143-188. https://doi.org/10.1007/10_2013_243
Qasem, N. A., & Abdulrahman, G. A. (2024). A recent comprehensive review of fuel cells: history, types, and applications. International Journal of Energy Research, 2024(1), 7271748. https://doi.org/10.1155/2024/7271748
Shrivastava, N. K., Chadge, R. B., & Bankar, S. L. (2017). Modelling and simulation of passive feed direct methanol fuel cell. International Journal of Energy Technology and Policy, 13(1-2), 4-18. https://doi.org/10.1504/ijetp.2017.080610
Shrivastava, N. K., Thombre, S. B., & Chadge, R. B. (2015). Liquid feed passive direct methanol fuel cell: challenges and recent advances. Ionics, 22(1), 1-23. https://doi.org/10.1007/s11581-015-1589-6
Soloveichik, G. L. (2014). Liquid fuel cells. Beilstein journal of nanotechnology, 5(1), 1399-1418. https://doi.org/10.3762/bjnano.5.153
Uhm, S., Choi, J., Chung, S. T., & Lee, J. (2007). Electrochemically oxidized carbon anode in direct l-ascorbic acid fuel cells. Electrochimica acta, 53(4), 1731-1736. https://doi.org/10.1016/j.electacta.2007.08.034
Umarkar, A. P., Chadge, R., Giri, J., & Shriwastava, N. (2024). Direct liquid fuel cell: challenges and advances. Recent Advances in Material, Manufacturing, and Machine Learning, 151-162. https://doi.org/10.1201/9781003450252-20
Valera-Medina, A., Xiao, H., Owen-Jones, M., David, W. I., & Bowen, P. J. (2018). Ammonia for power. Progress in Energy and combustion science, 69, 63-102. https://doi.org/10.1016/j.pecs.2018.07.001
Velisala, V., Srinivasulu, G. N., Reddy, B. S., & Rao, K. V. K. (2015). Review on challenges of direct liquid fuel cells for portable application. World Journal of Engineering, 12(6), 591-606. https://doi.org/10.1260/1708-5284.12.6.591
Xie, Z., Jin, Q., Su, G., & Lu, W. (2024). A review of hydrogen storage and transportation: progresses and challenges. Energies, 17(16), 4070. https://doi.org/10.3390/en17164070
Xing, S., Zhao, C., Liu, W., Zou, J., Chen, M., & Wang, H. (2021). Effects of bolt torque and gasket geometric parameters on open-cathode polymer electrolyte fuel cells. Applied Energy, 303, 117632. https://doi.org/10.1016/j.apenergy.2021.117632
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